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Electrochemistry

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The correct answer is A, chlorine.

  • The question describes the electrolysis of concentrated aqueous sodium chloride, which is also known as brine.
  • The main ions present are Na+, Cl−, H+, and OH−.
  • At the positive electrode (anode), anions are attracted. The competing anions are Cl− and OH−.
  • In concentrated sodium chloride solution, there is a very high concentration of Cl− ions. The high concentration makes it more likely for chloride ions to be discharged at the anode than hydroxide ions.
  • The product formed is chlorine gas.
  • The other products are hydrogen gas at the negative electrode (cathode) and sodium hydroxide in the solution.

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